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Evaluation of the
potential utilization of conventional and unconventional biomass
wastes resources for energy production
M.Torres,
P. Portugau, J. Castiglioni, L. Yermán and A. Cuña
2019/07/15
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Abstract
This work presents kinetic and thermal data
of three different biomass wastes with high availability in Uruguay. Samples
were analysed by proximate, ultimate and thermogravimetric analyses, transient
plane source, and a cone calorimeter. DTG results at different heating
rates allowed us to identify different stages during the thermogravimetric
analysis. Kinetic modelling per stages was realized for each stage observed
during the heating of the biomass samples. The kinetic was modelled minimizing
the square difference between the experimental data and theoretical values
obtained with the model. Activation energy values were obtained for each
stage, with values in the range 164-217 kJ mol-1 for the decomposition
of cellulose and hemicellulose, and between 190-507 kJ mol-1 for
the decomposition of lignin.
| Published in: Renewable Energy
& Power Quality Journal (RE&PQJ, Nº. 17) |
| Pages: 511-515 |
Date of Publication: 2019/07/15 |
| ISSN: 2172-038X |
Date of Current Version:2019/04/10 |
| REF: 360-19 |
Issue Date: July 2019 |
| DOI:10.24084/repqj17.360 |
Publisher: EA4EPQ |
Authors and affiliations
M.Torres1, P. Portugau1, J. Castiglioni1, L. Yermán2
and A. Cuña1
1. Area Fisicoquímica, DETEMA, Facultad de Química
Universidad de la República, Montevideo, Uruguay
2. School of Civil Engineering, The University of Queensland, Brisbane,
Australia
Key words
Kinetic modelling, thermal analysis, biomass, combustion,
cone calorimeter.
References
[1] Celebración de contratos de compraventa
para la producción de energía eléctrica a partir
de biomasa (Decreto N° 367/010), Uruguay, 2010. [Online]. Available
online: https://www.impo.com.uy/bases/decretos/367-2010
[Accessed 7Nov. 2018].
[2] M. Castelli, Evaluación de Proyectos de Microgeneración
Basados en Biomasa, Consultoría de apoyo al Componente: Políticas
Energéticas 2005-2030, Eje Estratégico: Diversificación
de la Matriz Energética, Ministerio de Industría, Energía
y Minería, Dirección Nacional de Energía, Uruguay,
2010. [Online]. Available online:
http://www.miem.gub.uy/sites/default/files/evaluacion_de_proyectos_de_microgeneracion_basados_en_biomasa.pdf
[Accessed 7 Nov. 2018].
[3] E.G.A. Forbes, R.J. Olave, C.R. Johnston, J.D. Browne, J. Relf, Biomass
and bio-energy utilisation in a farm-based
combined heat and power facility, Biomass and Bioenergy, Vol. 89,
pp. 172-183, 2016.
[4] L. Cutz, P. Haro, D. Santana, F. Johnsson, Assessment of biomass
energy sources and technologies: the case of Central America, Renewable
and Sustainable Energy Reviews, Vol. 58, pp. 1411-1431, 2016.
[5] 204M 1341 Plain Jacket Calorimeter Operating Instructions,
[Online]. Available online:
https://www.parrinst.com/products/oxygenbombcalorimeters/1341-plain-jacket-bomb-calorimeter/documents/
[Accessed 24 May 2018].
[6] O. D. Akinyemi, J. A. Olowofela, O. O. Akinlade, & O. O. Akande,
Thermal conductivity of soils with heavy metals
concentration from the Niger Delta region of Nigeria, Journal of
Zhejiang University. Science. B, 7(8), 615-8, 2006.
[7] Z. Yao, X. Ma, Z. Wang, L. Chen, Characteristics of cocombustion
and kinetic study on hydrochar with oil shale: a
thermogravimetric analysis, Applied Thermal Engineering, Vol. 110,
pp. 1420-1427, 2017.
[8] Y. Fan, Z. Yu, S. Fang, Y. Lin, Y. Lin, Y. Liao, X. Ma, Investigation
on the co-combustion of oil shale and municipal
solid waste by using thermogravimetric analysis, Energy Conversion
and Management, Vol. 117, pp. 367-374, 2016.
[9] G. K. Parshetti, A. Quek, R. Betha, R. Balasubramanian, TGAFTIR
investigation of co-combustion characteristics of
blends of hydrothermally carbonized oil palm biomass (EFB) and coal,
Fuel processing technology, Vol. 118, pp. 228-234, 2014.

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